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Q What are the factors an internal energy of the system depends upon? Q How can we say internal energy is a state function? Answer: Consider 1 mole of water is heated from K to K, the change in energy is 7. It is the same regardless of the form in...
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System A is in equilibrium with system C. System B is in equilibrium with system C. System A is in equilibrium with system B according to which law of thermodynamics? Possible Answers: The third law of thermodynamics The second law of thermodynamics...
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If gas A is in equilibrium with gas B and gas C, then gas be and gas C must be in thermal equilibrium with each other. Example Question 1 : Understanding The First Law Of Thermodynamics A gas in a closed container is heated with of energy, causing the lid of the container to rise with of force. What is the total change in energy of the system? Possible Answers: Correct answer: Explanation: For this problem, use the first law of thermodynamics. The change in energy equals the increase in heat energy minus the work done. We are not given a value for work, but we can solve for it using the force and distance. Work is the product of force and displacement. Now that we have the value of work done and the value for heat added, we can solve for the total change in energy. Report an Error Example Question 5 : Thermodynamics A gas in a closed container is heated, causing the lid of the container to rise.
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The gas performs of work to raise the lid, such that is has a final total energy of. How much heat energy was added to the system? We are given the amount of work done by the gas and the total energy of the system. Using these values, we can solve for the heat added. Example Question 1 : Understanding The First Law Of Thermodynamics A gas in a closed container is heated with of energy, causing the lid of the container to rise. If the change in energy of the system is , how much work was done by the system? We are given the total change in energy and the original amount of heat added. Using these values, we can solve for the work done by the system.
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For example, according to Joule, based on his experiments, energy supplied to a system in a form of heat, can be completely converted into work. But this process is not possible, because we know that in thermodynamic process internal energy of a system also increases. Thus, Heat transfer — Internal energy increase — Work transfer The complete conversion of heat into work is not possible. Therefore heat and work are not completely interchangeable forms of energy. It states that if energy is supplied to a system in a form of heat, which can be completely converted into work energy. But practically it is not possible, because internal energy of the system also increases in the process.
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Thus, first law of thermodynamics does not provide information on whether the change of state or the process is feasible or not. Consider the following heat engine, The heat Q1 is transferred to the system and work W1 is done by the system. Then system is taken to its initial position by applying work W2 on the piston and heat Q2 is rejected from the system. This is the heat engine cycle. In heat engine cycle, a net heat is transferred to the system and a net work is transferred from the system. In the system of mass of gas confined in a cylinder and piston machine, the heat is added to the system and work is done by the system on the piston and vice versa. In stem power plant initially the heat is added from the furnace to boiler, this stem passes through the turbine and work is done, then the stem is condensed to water in condenser and the heat is rejected from the system, and finally work is done on the system to pump the water back to the boiler.
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But refrigerator does not consist heat engine cycle, because in refrigerator, the work is done on the system and heat transfer takes place from the system. The main function of heat engine is to produce work output continuously by consuming heat energy given to the system. So the net work Wnet and heat supplied Qin to the system are taken into account. The net work output is the difference between work produces in the process and the work input required to take the system to initial state. In stem power plant, net work output is, Turbine Work WT — Pump Work WP Therefore, the efficiency of heat engine cycle is the ratio of total heat input to the cycle Qin to net work output of the cycle Wnet.
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These notes will help engineering aspirants in their preparation. Aspirants will have to focus on all subjects if they want to secure good rank in the examination. Students should try to prepare notes of all the chapters of all subjects during their preparation for the examination. To help aspirants to score good marks in coming WBJEE , the engineering section bring to you the notes of chapter Thermodynamics.
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Students always get questions from this chapter in the examination. Students can read the following topics here: 1. System and Surroundings, 2. Types of system open, closed, isolated , 3. Thermodynamic processes isothermal, adiabatic, isobaric, isochoric , 5. Sign conventions, 6. Extensive and Intensive properties, 7. Enthalpy and Entropy, 9. First law of thermodynamics, Relationship between Cp and Cv, Standard enthalpy of reactions, Enthalpy changes during phase transformations, Properties of enthalpy changes, Hess's law of constant heat summation and Calorimetry 1. These notes are prepared by Subject Experts of Chemistry. Important Concepts: The System and the Surroundings System: The part of universe in which observations are made is called system. Surroundings: It includes everything other than the system. For ex: heat given to system or work done on system is taken as positive Anything taken out of system is taken negative.
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Example: temperature, density, pressure Extensive property: This is a property whose value depends on the quantity or size of matter present in the system. Example: mass, total volume Standard enthalpy of reactions: It is the enthalpy change for a reaction when all the participating substances are in their standard states. It is defined as enthalpy change that accompanies melting of one mole of a solid substance in standard state. It is defined as amount of heat required to vaporize one mole of a liquid at constant temperature and under standard pressure. It is defined as the change in enthalpy when one mole of a solid substance sublimes at a constant temperature and under standard pressure 1 bar.
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It is defined as the standard enthalpy change for the formation of one mole of a compound from its elements in their most stable states of aggregation. It can be positive or negative. It is defined as the heat evolved when one mole of substance in standard state is oxidised completely. It is always negative. Properties of Enthalpy Change: It is an extensive property.
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Incorrect answer. Please choose another answer. Air Conditioning Heat which causes a change in temperature of a substance is called: a. Any time there is a change of temperature indicated by the thermometer the heat level or intensity can easily be measured. In the writings of the early scientists who provided the foundations of thermodynamics, sensible heat had a clear meaning in calorimetric. What is heat, which causes a change in the state of a material without a change in temperature, called?
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- 300 TOP MOST Thermodynamics – Mechanical Engineering Multiple Choice Questions And Answers
Latent heat c. Superheat d. Regular heat Heat, which causes a change of state without a change in temperature, is known as latent heat. An example of latent heat is water changing to ice or vice a versa. Latent heat is the heat released or absorbed by a body or a thermodynamic system during a process that occurs without a change in temperature. Commercial Air Conditioning What is a sling psychrometer used to measure? Wet and dry bulb temperature d. Barometric pressure A sling psychrometer is a device that consist of two thermometers fitted in a hinged bracket used for spinning the two thermometers. One of the bulbs is kept moist with distilled water on a sock or wick placed over the thermometer's tip.
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As the thermometers are rotated, evaporation of water from the wick lowers the temperature indicating a lower temperature than that of the dry-bulb thermometer. This is the Wet bulb temperature which will be lower than the dry bulb and can never be above dry bulb measurement. The lower the relative humidity, the lower the wet bulb temperature. The difference in the two bulbs readings can be applied to a psychrometric chart to calculate relative humidity and other properties of air.
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A compressor is operating with a discharge pressure of What is the compression ratio pumping ratio? PSIG is converted to absolute by adding In this problem, discharge pressure Commercial Refrigeration 7. In a direct expansion evaporator, liquid refrigerant must boil away as close to the end of the coil as possible in order to: a. Direct type evaporators are designed to operate most efficiently with approximately 10 degrees superheat. In order to have superheat, all liquid must be boiled away before reaching the end of the evaporator. Heat Pump Service What is the major difference between a heat pump and an air conditioner? Condenser c. Evaporator d. Reversing valve The reversing valve is the component that will reverse the flow of refrigerant when changing from air conditioning to heating. What device controls the supplementary electric heat according to the outdoor temperature? Auxiliary temperature control c.
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- Thermodynamics Multiple Choice Questions And Answers
Outdoor ambient thermostat d. Indoor thermostat only To control energy, the heat pump will incorporate outdoor thermostats to limit the auxiliary heat before the balance point is reached. Heat Pump Installation Which of the following is not a factor that should be considered when installing an outdoor unit? Return air c. Sound transmission d. Snow fall When installing the outdoor unit the return air is not a factor in the installation; all of the other answers are factors involving installation.
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What is the minimum clearance for access panels on an outdoor condensing unit? One BTU is the quantity of heat required to raise the temperature of one pound of water one degree Fahrenheit. What is the primary composition of natural gas? Electric Heat The electric heat element is usually made of what material? Copper with a brass coating b. Nickel with a cadmium coating c. Nickel and steel d. Nickel and chromium Heat elements are made of Ni-chrome which is nickel and chromium.
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Assessment 4: Phase Transition Indicative marking scheme, parts 2,2,2,4,4,3,4,4. You should attempt the tutorial problems in advance of the problems class feedback session. Both lectures and tutorials will cover theory and the practical application by relating it to physical systems which are somewhat familiar. Feedback forms There will be various opportunities to give written feedback through the year. I hope you find it cathartic. I will respond to it and, judging by previous years, you won't look at my response. Lecture Notes Notes for all lectures are available here, they may be subject to minor changes. There are two demonstration lectures without formal notes, but the material therein is still examinable. Section 1: PDF Systems, surroundings and thermodynamic variables; work and equilibrium introduced.
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Section 2: PDF Processes. Partial Differentials and state functions. Section 4: PDF Cyclic processes: heat engines. The Second Law of Thermodynamics. Carnot's Theorem. Section 5: PDF Thermodynamic temperature scale. Carnot devices. Entropy, and principle of increase in entropy. Entropy, probability and disorder. Maxwell's relations. Magnetic systems -- refrigeration. Phase equilibrium. Calculating Entropy. The Clausius-Clapeyron equation. The vaporization curve. First order phase changes. Second order phase changes. Exercises Weekly tutorials will be available here, taken from the free online ebook. Prof Ackland and a team of postgraduate students will act as course tutors. Prof Ackland is easily distracted by discussions of other interesting aspects of physics. This year's demonstator team is. Solutions to Exercises Extensive and discursive answers to the tutorials are provided online. Single-semester visiting students and Geosciences students have a bespoke "Thermodynamics" paper at the end of the first semester.
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There is a resit paper in August for those who qualify. Previous Examination Papers can be found via the central University Library site. This requires an Edinburgh University login. Only the May diet are published, December diet questions are similar to questions A and section B in those papers. The December exam has three short "Section A" questions and one out of two long "Section B" questions. Although there will always be some rote-learnable sections, the examination questions will probe whether you understand what you've been taught, not simply whether you can remember it. The purpose of this course is to teach you some physics, not to help you pass the examination.
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But if you are interested in passing the examination, it is a good idea to practice with some past papers. Remember that while a tutorial problem gives you practice at testing you own understanding, an examination answer also requires you to communicate that information to another human being who marks the paper. However, this will not compromise in any way the in-class experience.
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A decent 1 minute online talk takes about an hour and multiple takes, so don't expect TED talk standards. If you have to miss a lecture, please look through the notes and Prof. Ackland will be happy to discuss anything at the tutorial. Overheads There is nothing of use in the lecture overheads which is not already contained in the notes. They are subject to random, unpredictable changes and not intended to make any sense whatsoever without the soundtrack.
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For most of the engineering purposes, heat capacities may be assumed numerically equal to specific heat values. For an aqueous solution of salts, the specific heat can be estimated by assuming the specific heat of the solution equal to that of the water alone. Give examples of latent heats. For pure substances, the heat effects accompanying changes in state at constant pressure no temperature change being evident are known as latent heats. Examples of latent heats are the heat of fusion, vaporization, sublimation and change in crystal form. What is their significance and importance? It is equal to the work during a constant-volume isothermal reversible nonflow process.
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For reversible isothermal steady-flow processes or for reversible constant-pressure isothermal nonflow processes, change in free energy is equal to network. Isothermal process. Volume remains constant. Throttling process. All the mechanical engineering systems are studied with the help of thermodynamics. Hence it is very important for the mechanical engineers. There are three laws of the thermodynamics: First Law: Energy can be neither created nor destroyed. It can only change forms. In any process in an isolated system, the total energy remains the same. Second Law: When two isolated systems in separate but nearby regions of space, each in thermodynamic equilibrium in itself, but not in equilibrium with each other at first, are at some time allowed to interact, breaking the isolation that separates the two systems, and they exchange matter or energy, they will eventually reach a mutual thermodynamic equilibrium. The sum of the entropies of the initial, isolated systems is less than or equal to the entropy of the final exchanging systems.
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In the process of reaching a new thermodynamic equilibrium, entropy has increased, or at least has not decreased. Third Law: As temperature approaches absolute zero, the entropy of a system approaches a minimum. It can only be transformed from one form to another. Is the boiler a closed system? Yes definitely the boiler is a closed system.
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Gibbs Helmholtz formula is the formula which forms the link between the thermodynamics and electromagnetism. Give Its Limitations And Importance.? For example: The entropy of pure carbon dioxide and nitric oxide is zero at 0K. This shows that there exists disorder in the arrangement of such molecules. This law is applicable only to pure compounds. Thus we can say that, this law is not applicable to glass which is a supercooled liquid. It is also not applicable to amorphous substance and supercooled solutions. Importance: With the help of this law Thermodynamic properties can be calculated and chemical affinity can be measured. This law helps in explaining the behaviour of solids at very low temperature.
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Zeroth law: If any two systems are in thermal equilibrium with the third system, then they are also in thermal equilibrium with each other. First law: First law of thermodynamic states that energy can neither be created nor be destroyed but it can only be converted from one form to another. Isolated system: A system that can neither exchange matter nor heat with the surrounding is known as an isolated system. For example: Water placed in a vessel that is closed as well as insulated. Open system: A system that can exchange both matter and energy with the surrounding is said to be an open system. For example: A reaction taking place in an open vessel exchanges both energy and matter with the surrounding. Closed system: A system that exchanges only energy and not matter with the surrounding is said to be a closed system.
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For example: A reaction taking place in a closed metallic vessel. This thermodynamic quantity states that the decrease in value during a process is equal to the useful work done by the system.
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Ans: c Which of the following can be regarded as gas so that gas laws could be applicable, within the commonly encountered temperature limits. Ans: d The unit of pressure in S. A closed system is one in which a mass does not cross boundaries of the system, though energy may do so b mass crosses the boundary but not the energy c neither mass nor energy crosses the boundaries of the system d both energy and mass cross the boundaries of the system e thermodynamic reactions take place.
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Ans: a Temperature of a gas is produced due to a its heating value b kinetic energy of molecules c repulsion of molecules e surface tension of molecules. Ans: b According to kinetic theory of gases, the absolute zero temperature is attained when a volume of the gas is zero b pressure of the gas is zero c kinetic energy of the molecules is zero d specific heat of gas is zero e mass is zero. Kinetic theory of gases assumes that the collisions between the molecules are a perfectly elastic.
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Ans: c Which of the following can be regarded as gas so that gas laws could be applicable, within the commonly encountered temperature limits. Ans: d The unit of pressure in S. A closed system is one in which a mass does not cross boundaries of the system, though energy may do so b mass crosses the boundary but not the energy c neither mass nor energy crosses the boundaries of the system d both energy and mass cross the boundaries of the system e thermodynamic reactions take place.
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Ans: a Temperature of a gas is produced due to a its heating value b kinetic energy of molecules c repulsion of molecules e surface tension of molecules. Ans: b According to kinetic theory of gases, the absolute zero temperature is attained when a volume of the gas is zero b pressure of the gas is zero c kinetic energy of the molecules is zero d specific heat of gas is zero e mass is zero. Kinetic theory of gases assumes that the collisions between the molecules are a perfectly elastic.
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For example, according to Joule, based on his experiments, energy supplied to a system in a form of heat, can be completely converted into work. But this process is not theromdynamics, because we know that in thermodynamic process internal energy of a system also increases. Thus, Heat transfer — Internal energy increase — Work transfer The complete conversion of heat into work is not possible. Therefore heat and work are not completely interchangeable answsrs of energy. It questioms that if energy is supplied to a system in a form of heat, which can be completely converted into work energy. But practically it is not possible, because internal energy of the system also increases in the process.
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Thus, first thermodynamkcs of thermodynamics does not provide information on whether the change of state or answwrs process is thermodynamics exam questions and answers or not. Consider the following heat engine, The heat Q1 is transferred to the system and work W1 is done by the system. Then system is taken to its initial position by applying work W2 on the piston and heat Q2 is rejected from the system.
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This is the heat engine cycle. In heat engine cycle, a net heat is transferred to the system and a net work is transferred from the system. In the system of mass of gas confined in a cylinder and piston machine, the heat is added to the system and work is done by the system on the piston and vice versa. In stem power plant initially the heat is added from the furnace to boiler, this thermodynamics exam questions and answers passes through the turbine and work is done, then the stem is condensed to water in condenser and thegmodynamics heat is rejected from the system, and finally work is done on the system to pump the water back to the boiler.
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But refrigerator does not consist heat engine cycle, because in refrigerator, the work is done on the system and heat transfer takes place from the system. The main function of heat engine is to produce work output continuously by consuming heat energy given to the system. So the net work Wnet and heat supplied Qin to the system are taken into account. The net tehrmodynamics output is the difference between work produces in the process and the work input required to take the system to initial state. In stem power plant, net work output ansswers, Turbine Work WT — Pump Work WP Therefore, the efficiency of heat engine cycle is the ratio of total heat input ansders the cycle Qin to net work output of the cycle Wnet.
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In what way is it different from bond enthalpy of diatomic molecule? Therefore, the reaction will not be spontaneous below this temperature. Thermodynamics, Equilibria and Electrochemistry All the commercial liquid fuels are derived from natural petroleum or crude oil. What will be the direction of the reaction at this temperature and below this temperature and why? What is the change in entropy in the system when If the system as a whole is at rest, so that the bulk mechanical energy due to translational or rotational motion is zero, then the Which of the following are open close or nearly isolated system?
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Explanation are given for understanding. With the help of AI we have made the learning Personalized, adaptive and accessible for each and every one. Formula sheet. Enthalpy change for 0. Explain both terms with the help of examples. We respect your inbox. Thermodynamics Center For Teaching amp Learning. Give suitable examples. Average bond enthalpy is average heat required to break 1 mole of particular bond in various molecules polyatomic. You are on page 1 of Ans: d 2. According to Gibbs Helmholtz equation, i No heat is absorbed by the system from the surroundings, but work w is done on the system. Thus, entropy increases. Internal energy change is measure at constant volume.
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You will get here all the important questions with answers for class 11 Chemistry Therodynamics and chapters. Compute the molar heat capacity of these elements and identify any periodic trend. That will be very helpful in quick revision during Exams. If there is trend, use it to predict the molar heat capacity of Fr. Zeroth law of thermodynamics. Also calculate enthalpy of solution of ammonium nitrate. Specific heat and latent heat of fusion and vaporization. Is there any enthalpy change in a cyclic process? Much more Here all the important questions with answers by … all the important questions and answers to practice and learn concepts Are updated with respect to upcoming Board exams if not at what,. Trivia quizzes to test your knowledge on the system Engineering thermodynamics by T. Also get to know about the strategies to Crack exam in limited time period Engine will?! View free Study Material and much more Sol, e. Will not be spontaneous below this temperature can Study anytime anywhere of phosphorus reacts with excess Do mechanical work as burning of fuel in an Engine, Siesel Engine will?.
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